Problem Solved
It took me some time, but I have tried to install the database and Calibre on a single stand alone PC and Yes! It worked well since that single install.
It is a bit confusing that a drive in Windows as a part of a NAS cannot be used as location for de Calibre database. Strange also, that I have used Calibre a long time in that manner without any problems. I think there has been a change in Windows or in Synology DSM, so the problem occured since?
Anyway, I now know the reason why Calibre didn't worked.
Thanks for helping!
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