I checked my setup as well - there are no spaces in the path to my fonts (C:\Users\ddgra\Documents\eBooks\Fonts) but the temporary files folder had spaces (C:\Users\ddgra\Documents\eBooks\Sigil Temp Docs). When I changed the temp folder to not have spaces the open with works fine.
'Twould be convenient, though, to double-click a font file and have it open automatically in the main window, like images do. But certainly not critical.
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