Check the epub2 and epub3 standards for recognized file types. Epubs are not web pages. The latest is here. webp images are not in the supported core media list.
https://w3c.github.io/publ-epub-revi...epub-spec.html
So even if Sigil added it, it can not be used in epub2 at all and can only be used in epub3 if you specify a fallback resource which I have never actually seen.
I would be happy to add support to webp images to Sigil if you provide references for the proper media-type. But many validators and many existing ebook readers will not support it as it is not a supported core media type even in the latest epub3 spec.
So choosing webp for a epub is probably not a good choice.