I have a Kobo reader that I like. But I don't sync. I suggest asking in the Kobo forum how well it syncs between the Kobo and the Kobo app for Android.
The problem with syncing is that you end up having to keep WiFi on. That drains the battery faster. Personally, I would have different books on the Reader and on the app. That way, you don't need WiFi on and you don't have to worry about syncing. It's not hard to have two different book on the go.
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