I ran into a similar issue with one co-worker. He and his wife have been using the same Amazon account for several years. When they were splitting up, she got to retain the Amazon account while he got to keep the dog. What we did was to have him create a new account on Amazon, de-register his Kindle app on his iPad and register it to his new account, setup calibre and the Kindle app on his laptop with the old account settings, download all the purchased ebooks, bring them into calibre removing the DRM and email them to his new Send-to-Kindle email address. About 130 ebooks in total so this worked for him.
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