. put the calibre library outside of a user area e.g. at c:/calibre LIbrary and all users will have access
. the program itself installs to program files, which is shared by all users
. by default , each user will still have their own interface preferences still as the config folder is in a hidden user specific folder. ; in app data roaming
probably that is also movable to a common area without any problems but seek a 2nd option if it matters
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