I think easiest way (apart from using CC supported cloud service) is to use the same filename template for CC and pCloud copies.
Personally, I actually have 2 sets of my books on Dropbox:
One is a complete/direct mirror of my Calibre library (my offsite backup)
The other uses {genre}/{author}/{author} - {series} {series_index} - {title} (for easy browsing on Marvin for iOS).
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