I think we need more information from the OP before deciding where this thread should be moved. Calibre does not directly support iBooks so I would suspect either he is using calibre server as a web interface with it's read/download or Calibre Companion as a pseudo-device.
IIRC, calibre server will open the book in the web interface if Read is selected, you need to select Download to open it in another application.
Edit: just checked and that's how it works on my iPhone. Read opens the book in the web interface while Download offer to open it in Books.
Last edited by DNSB; 06-15-2019 at 02:25 PM.
Reason: Tested read vs. download
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