New books appear at the top. I have the same tweak you do. I only add books from within Calibre, i.e. drag-and-drop or the Add Books dropdown for compressed files.
What it's doing is sorting by date *and* by whatever other column I happened to last click. So if I clicked the Format column, then Date, it'll re-sort by date then format. If I clicked Size then Date, it'll re-sort by date then size.
I just want it to sort by date and only by date.
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