i can't help you with the sony library software because i don't use it at all, but i do use calibre with my 700. since i use it exclusively i've never had any compatibility issues, but i am pretty fastidious about making sure the meta-data is correct so usually i add books one at a time and edit the meta-data by hand (keyboard shortcut E, or just double click on the field in the library view ; you can also use ctrl click or shift click to select several books and batch edit the meta data ; this is good for adding authors, or series name, or tags to create collections).
what problem exactly did you have ?
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