From calbre's website, which also uses Qt, Kovid lists a number of Windows 10 apps that seem to cause problems with calbre (and therefore most likely Sigil too). Are you by chance using/running any of the following:
The following programs have been reported to cause crashes in calibre: If you are running any of these, close them before starting calibre, or uninstall them: RoboForm, Logitech SetPoint Settings, Constant Guard Protection by Xfinity, Spybot, Killer Network Manager, Nahimic UI Interface, Acronis True Image.
Another thing to try is to reboot your Windows box into safe mode, and try running Sigil to make sure Sigil is not clashing with Windows extensions, some of which are written using incompatible versions of Qt.
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