The location of the main book folder can vary somewhat by device, but it will be something like "/sdcard/Android/data/com.amazon.kindle/files" or "/storage/sdcard1/Android/data/com.amazon.kindle/files/Books/amzn1.account.xxxxxx". Each book is contained in a separate sub-folder named with the ten character ASIN of the book.
Even if you locate the book file you won't be able to do anything with it in most cases. Most books have DRM and as far as I know there is currently no working method for DRM removal from the Kindle for Android app. Even if the publisher has requested that the book be made available without DRM, if it has Enhanced Typesetting then it will be in KFX format and cannot be converted from Kindle for Android.
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