Keep in mind that there are some fonts that are simply incompatible with ADE. I con't remember the exact name of the property, offhand. But there was a certain version-level that determined whether ADE would support it. It was a property that could be easily modified in FontForge (or something similar). If your font is opensource, it should be possible. Someone else will have to provide the details, though.
But none of that will matter until you get it working in Sigil.
The only things I can recommend are using the Tools->Validate Stylesheets feature of Sigil to ensure there are no syntax errors (as Toxaris mentioned) and to double-check that the CSS is indeed linked to the html file.
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