There is no Calibre on Android but there are a number of ebook reader apps available. There's Calibre Companion on Android and this version is actually more advanced than the iOS one.
However, there are usually plenty of ways to transfer books from Calibre (on Linux/Mac/Windows) to Android tablets (USB, SD card, wireless, cloud storage). You also have access to the file system similar to your computer. Lack of file system access can be a deal breaker for some users that they wouldn't even consider iOS.
Note, I do use iOS devices for reading (primarily with Marvin) but I've learned to work around its limitations. I use Calibre's Content Server or Dropbox to transfer content.
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