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Perhaps you might consider downloading Calibre Portable onto the drive, then copying the configuration folder from "roaming" onto it, then do a straight up copy of the entire library folder to the drive. If you do it right you can open the Calibre and point it to the downloaded library on the flash drive and all your settings should follow. I did that when I needed an "extra" Calibre to point to redundant libraries on a drive but didn't want it to stay on my computer.
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