in the program preferences you activate sync to ( cloud of your choice) and choose either sync the entire book or only sync the annotations... ( if you choose the former then Moon will upload a copy of the pdf to its books folder in cloud)
if the program is on two devices then obviously you set that on both
but AFAIK Moon+ is an android only program - there is no PC version- so no way to move your annotations to / from PC.
PS when you open a book in moonreader, it creates a database entry in its own database for book location, metadata etc, it does not make a copy of the book.
i know of no reader that works in android AND on PC, Bookari has its own cloud which is accessible from a browser, but the app is android only
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