Probably a key assignment conflict issue. Please note, Sigil has its own mechanisms to assign key combinations to functions. On a Mac, the OS overrides many of these preventing the assigned keys from working (this is especially true for Function keys). Adding Quickkeys on top of this just makes things worse. So check your OS level keyboard assignments, your quickkeys assignments and then check and re-assign the Sigil keyboard assignments via Sigil Preferences and you should be able to get things to work.
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