The Synology GUI works (DSM 5) on port 5000 (unless you changed it?
The (apache) webserver on the Synology should work with port 80 (or 443 for https: access).
When you try to access your Synology GUI from outside of your LAN (through internet) do you use:
http://<your-external-url-or-ip>:5000 ?
And for cops?
http://<your-external-url-or-ip>:5000/cops ?
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