@Lemmi: Looking at the log file, the error is in code to do a dump a copy of the output into another directory for debug purposes. I assume the permissions of the destination directory are the problem. This looks like "E:\Download\temp". This is set in the "Debug" settings at the bottom of the conversion dialog.
As to why it is only happening with conversion to kepubs, is it only one book? The conversion settings are stored with each book when you do a conversion. They are reused if you do another conversion. If you have this error, and try the conversion again before fixing problem, it will happen again. Clearing the debug option should solve this, or fix whatever the permissions problem is.
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