When you sort series in ascending order, items without a series sort before items with a series. When you sort them in descending order they sort after. Perfectly sensible, if you ask me. If you want to see a list with only series in it, click "Series" in the tag browser on the left and then sort however you want.
And I have no idea what you are talking about with regards to zip files. If you mean that while calibre is importing a zip file, you cannot open it in other programs, that is thanks to Microsoft, since windows does not allow files to be opened in more than one program at a time. You dont like it, complain to Microsoft.
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