Compare the details of the devices, the Nook S2s are basically the low end of the models. Smallest internal storage available, etc. Also keep in mind that should you have issues with the device, Samsung will send you to B&N to resolve them, and B&N has a sketchy history supporting their devices. In particular as the device is replaced by a newer model.
To put it simply, is the savings worth a potential headache down the line if anything goes wrong with the device?
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