Remember there need be zero correlation between the sequence of files within the ePub and the sequence that is displayed by a tool like calibre or Sigil (or even WinZip, or any other graphical tool).
The issue is not what order they are stored within the ePub, rather your issue is the order that Sigil or any other tool decides to display the entities in its file selection browser.
If you want to see the order these files appear in the ePub itself your best bet would be to use one of the command line zip utilities to display the 'directory' of the ePub file since it nothing more than a renamed zip file with the requirement that the first entry in the directory is 'mimetype'*which contains the 'string*application/epub+zip' and be stored uncompressed, and unencrypted.
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