It's as if it's not really logging you into your account. It's obviously not getting your current key. Entering your cc info does no good for new downloads because that's not what the key is based on any more. But, of course, Nook for PC doesn't know that.
I didn't intend for it to be a solution or even a work-around. Just a test to get an idea of what was happening.
Here's something that might fix the problem, but I make no promises. Read through it and proceed at your own risk if you think it's worth a try. Cut & paste this in to the Windows Explorer address bar: %APPDATA%\Barnes & Noble\BNDesktopReader (It's a hidden folder.) Move the ClientAPI.db file out of that folder. (You can also delete or move any books you don't want in "my stuff" from the My Barnes & Noble eBooks folder in your Documents folder.) Then open Nook for PC, log in to your account, and see what happens. If this somehow leaves you worse off than before, you should be able to reverse it by deleting the new ClientAPI.db file and moving the old one back.
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