OK - that gives me something to work with.
I thought that with the metadata in a database it should scale reasonably well as the metadata.db file is not that large (only a few megabytes), but as I was having problems I though I would check. I was also concerned that I might be encountering an issue that was Windows specific.
Anyway I will report back when I have more information. It may well be something local to my system and not related Calibre at all.
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