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Certainly can't choose one....but
Nonfiction:
The Selfish Gene by Richard Dawkins
and
Engines of Creation by Eric Drexler
and
The Psychopathology of Everyday Life - Freud
Fiction:
Dhalgren - Samuel R. Delany
Foundation Trilogy - Asimov
Grapes of Wrath - Steinbeck
Ringworld - Niven
....
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