@jecilop - close calibre, copy the existing calibre configuration folder to where you want it to be, rename it if you're inclined, then follow the arrows in the attachment.
The path to the new location must be precise, best to cut & paste from Windows Explorer address bar
Now rename the original calibre configuration folder to say calibresave
Run calibre and go to Prefs->Misc-> and click the Open... button. If it opens at your new location then success, back it up, and then go delete calibresave.
BR
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