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thistlebarrow2 - I wonder if you accidentally 'removed' the library from calibre's demesne.
I've done it too many times to count. Its easily fixed:-
- click the library icon;
- select Switch/Create library;
- click the blue button;
- browse to the library folder;
- click OK;
- ensure Use the previously existing library at the new location is selected;
- click OK.
BR