http://manual.calibre-ebook.com/faq.html#id36
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Where are the book files stored?
When you first run calibre, it will ask you for a folder in which to store your books. Whenever you add a book to calibre, it will copy the book into that folder. Books in the folder are nicely arranged into sub-folders by Author and Title. Note that the contents of this folder are automatically managed by calibre, do not add any files/folders manually to this folder, as they may be automatically deleted. If you want to add a file associated to a particular book, use the top right area of Edit metadata dialog to do so. Then, calibre will automatically put that file into the correct folder and move it around when the title/author changes.
Metadata about the books is stored in the file metadata.db at the top level of the library folder This file is is a sqlite database. When backing up your library make sure you copy the entire folder and all its sub-folders.
The library folder and all it’s contents make up what is called a calibre library. You can have multiple such libraries. To manage the libraries, click the calibre icon on the toolbar. You can create new libraries, remove/rename existing ones and switch between libraries easily.
You can copy or move books between different libraries (once you have more than one library setup) by right clicking on a book and selecting the Copy to library action.
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You can open a book by clicking the correct format in the book details pane at the right side. (or by Alt-V) Right clicking lets you delete a file and other options.
http://manual.calibre-ebook.com/gui.html#book-details
If you paste your list into WordPad or whatever the libre office word processor is it should do the spacing a bit better than notepad.
To do it in WordPad. select text , right click on selected text, uncheck the box for adding space between paragraphs and it will be nicely spaced.
Helen