I don't think so. All the books I have read have the epub directly converted from PDF.
Thought, I also did contact them about uploading custom epubs for better viewing and to help other people and here was the response:
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Can I make a custom formatted epub version an already available pdf book and upload it here?
I asked the second question because I have seen like the currently borrowed book of mine which is "Sweetheart, Sweetheart" by Bernard Taylor, is available as an epub as well but the formatting is very bad as it seems to be a direct conversion of the PDF and seems slightly more difficult to read than the PDF.
Quote:
We don't have a mechanism to use alternative EPUBs at this time.
Thanks for using openlibrary.org and archive.org
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I also put up the question on archive.org
here.