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ADE hardcodes the location of the My Digital Editions folder, you cannot point it to a new location. You can remap your Home Folder to a new drive, or use symlinks to redirect "C:\Users\<username>\My Documents\My Digital Editions" elsewhere, but you cannot tell ADE to look in "D:\my ebooks folder".
It's probably less effort to google "apprentice alf" and follow the directions to make calibre the true home of all your books.
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