maybe you need to see what cached-write settings windows is using on the networked drives. Your issues may go away if you disbale all write caching - just a thought.
by default AFAIK windows sets removable drive to don't cache, fixed drives to cache - not sure what it does with network mapped drives...
As what works for others is not working for you, and you all have the same calibre software, it is likely that windows file management settings are the differentiating factor.
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