You should get a file browser for your device as well. I use ES File Explorer. Using that app I can connect to my NAS over wifi and play movies directly from the share or copy over folders with mp3 files or with ebooks or other media.
For ebooks I use calibre to manage them on my computer, and then save them to a shared folder on my NAS. And use the app FolderSync to automatically keep a folder on my device synced to the folder on the NAS, over wifi.
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