Quiet frankly I am doubting if you are close to putting it on the Kindle. It seems that you still have to find your way into Sigil...
The first file is always there when you create a new book with Sigil. If you do not want to use that empty xhtml, remove it from the book browser (right click on it). It will not be gone magically. Also, your images must be both in the images folder and must be referenced to in the html. Please ensure that the paths to the images are correct: "../Images/<imagename>".
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