Well, to answer your main question, NO. The sony does not support Mobi (.prc) files natively.
It does however support plain Text (.txt) and Rich Text (.rtf) files natively along with BBeb Files.
If you do have Mobi files already and if they are unprotected (No Drm) you can easily convert them using the free program Calibre. It also allows you to manage your reader library if you don't want to use Sony's own program.
If you've got DRM protected files you're going to have to remove the DRM to convert and load them onto the Sony. For Mobi do a Google search for Mobi DeDRM and for Microsoft Reader (.Lit) ConvertLIT.
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