I'd save a copy, then delete:
/* Font Definitions */
@font-face
{font-family:SimSun;
panose-1:2 1 6 0 3 1 1 1 1 1;}
@font-face
{font-family:"\@SimSun";
panose-1:2 1 6 0 3 1 1 1 1 1;}
and
font-size:12.0pt;
font-family:"Times New Roman";
and see how that goes.
That way the Kindle can select the size and any fonts it can display.
What Sigil displays in set in preferences and has nothing at all to do with what the reader will display, unless fonts have been loaded and referred to. Arial and Times New Roman are licensed fonts which should be avoided and open source fonts used instead if you wanted to specify a particular font.
Not a bad idea to load enough of a font for a fancy chapter start or something, but a complete font set can take up a fair amount of space in the reader and be a headache for you getting the thing to display, especially in some older readers.
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