For what it's worth, I run Calibre against a shared network drive all the time. But I'm VERY careful to always close Calibre on Machine A before opening it on Machine B. My Calibre library is on a network share from a domain joined Windows Storage Server Essentials box, with permissions set to full for everyone.
This would be a total disaster if anyone tried to access the share except me, and if I got careless and forgot to close Calibre. (I know, cause I've had to rebuild it when I forgot!) That being said, it is useable for my very carefully controlled environment.
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