First of all, a big Thank You to all the people who took some time to reply. I am a bit wiser now.
The book seems to be fixed now. I had a few more problems with the TOC and the relative linkage (easily fixed), but it now validates perfectly and works like a beauty on my Sony ereader. Mobi conversion turned out great too.
My only remaining fear is that the 314K single-part file might be too large for some older/weirder readers... but I really wouldn't know what else to do.
The good news is that this was the Italian edition of the dictionary, so when the English-language translation will come out I will adopt a wiser (NOT Word > Dreamweaver > Calibre > Sigil) approach.
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