As AnemicOak said, go to the Kobo shop and download the epub or other version of the book.
You can add books from the device to the calibre library. But, the driver deliberately blocks adding kepubs. This is because calibre has no support for them and any DRM in them makes it impossible to do anything with them. If you do want to look at them, find the book in the device list and select it. The details section will display the path to the file.
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