There should be an icon on your toolbar when your device is connected, which if I'm remembering correctly is called 'Device'. Click on that, and it should show you the items on your device.
There should also be a flag on the items in your library for those items that are on your device. At the bottom of your library list there is a scroll bar. Scroll it to see if you can see it. If the field is not there, you can always add it (again if I'm remembering correctly) through the preferences tool bar. I'm not in front of my 'Calibre computer' right now so can't verify. If I'm wrong, someone can correct me, or I'll correct when I get home.
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