All tablets with operating systems of honeycomb, ice cream sandwich, jelly bean and up use mtp and this is not recognized by Windows XP. Windows XP does not have mtp capability.
The reason why the bookcovers are not showing up, is when you send to kindle a pdoc identifier is attached to the book which identifies it as a doc file. Instead of doing that I'd recommend using drop box and the usng save to disk to drop box then just downloading the books you want to read from there.
My computer at work has Windows XP, so my portable calibre doesn't work recognize my Fire HD. So when I want to read something not on my fire HD, I download it off my dropbox account.
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