Hi Fraser - welcome to the forum.
Calibre does have the ability to do what you want. I personally use Calibre to host all of my books on my own personal server so I can access/manage my library from (literally) all over the world.
If you go into the "Calibre" forum you will be able to find several threads on how to set it up. Search for "ODBC" or "server".
Cheers!
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