Open Calibre, go into preferences, select metadata plugboards, then create a new one using the following settings (I know it says kindle2 but it works on my K3 and should on the PW):
format: mobi
device: kindle2
template: {series}{series_index:0>2s| - | - }{title}
destination: title
From then on when you send a book to your Kindle or save to disk, the books will be named... Series - 01 - Book Name (i.e. A Song Of Ice And Fire - 01 - A Game Of Thrones)
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