On my K2i, if I open Calibre and then attach my kindle via USB, I can view the books on the 'Device'....this page in Calibre also has the ability to highlight individual books and then upload them to the Calibre library from my 'Device'. Of course you may need a plugin from our special friend to deal with any DRM issues that may present as you upload the book.
As far as I know, there is no plugin yet to deal with the DRM issues from Fire. (if I'm wrong on this one, I'd love to have someone let me know!)
Good luck!
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