@ Toxaris:
The above post was copied directly from the opf and ncx files, which I opened with <alt> f1, clicking on content.opf, and looking at the file in Code View. Ditto for the toc.ncx.
If you can tell me what it is that you are looking for in the above files, I can copy and insert it for you.
By the "Generate TOC" button, do you mean the one at the bottom of the Table of Contents menu that appears after keying <alt> f3? As far as I can tell, the files generated then look exactly like those above.