I know that you can add chapters AFTER the ones you already have, but can you place the newly added chapters BEFORE the list of chapters?
For instance, if you have Chapters 2 and 3 already, can you insert a chapter 1 and place it BEFORE chapter 2?

How about a table of contents section? Can you add it and place it before all the chapters in the book?
I'm using Sigil 0.3.4 on SuSE Linux 11.4 64 bit, and the loaded Qt is 4.7.1