If you Open the pdf while reading the email it is attached to (using the button that appears), it first downloads it to the Nook and then opens it. You can then find it later in Library>MyNook>MyFiles>My Downloads. You can then open it again (read it), delete it, etc.
I don't know any way to save it to the Nook without opening it in the email program when you are looking at the email it is attached to.
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