The TOC would depend on the book, I think - some have one, some don't. The Nook does not generate one for you, if that is what you are wondering. If the book does have one, almost always you can pick the entry you want via the touch screen (again, this assumes that the editor of the e-book used correct coding techniques).
As far as page numbers, I can tell you that page numbers remain accurate between devices. For example, if I open a book on the Touch or the Color Nook or even Nook for PC (I think also in the Firefox browser plugin), and go to a particular page, they all have the same text. This can be very handy.
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