As was mentioned above and I didn't realize, I guess the option to download the AZW file directly is only available if you actually own a physical Kindle device because it would be found in the exact location you described. I checked mine and the only device I can download for is the actual Kindle, not the PC app or the iPad app. I know that when you download the file from there, it is tied with DRM to that specific device so I guess if there isn't a device they can't do this.
I haven't used a file explorer app in awhile, I think the one I used was Disk Aid which lets you explore for free. I did a search and the first program that came up was called iExplorer which looks like it does the same thing.
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