Thank you, theducks. Actually I made it work without doing that (I always plug the external drive in the same place, so I haven't had problems with the drive letter yet).
Like I said, what does the trick is running Calibre as administrator. Still, this causes a new problem: drag and drop of ebooks stops working. It happened to me, and I saw in another thread that that was the problem. I can live without drag and drop, but I thought I'd mention it because it's a collateral effect of the solution.
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