You have to edit the book file itself -- if there isn't anything entered in the proper place within the file for the title, the book will be listed by the name of the file. If there is something inside the file in the location for the book title, that's how it will be listed.
Some book files you might be able to edit with Calibre, but the commercial lrx files can't be edited.
Maybe you could be more specific about what you want to have changed and people could offer insights about how to do it?
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